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Abstract

A study on the use of MCM-48-nCaO as a catalyst in the esterification reaction of nyamplung seed oil (Calophyllum inophyllum L.) has been carried out. The characterization results of XRF, XRD and FTIR showed the success in the synthesis of heterogeneous catalysts, MCM-48- nCaO, using a grinding-impregnation method. Through esterification reaction using the catalysts, FFA content in the seed oil of nyamplung reduced from 28 to 1.7%.

Keywords

Nyamplung seed oil MCM-48-nCaO esterification

Article Details

How to Cite
Kolo, L., Firdaus, F., & Taba, P. (2017). THE USE OF MCM-48-nCaO AS CATALYST IN ESTERIFICATION REACTION OF NYAMPLUNG SEED OIL (Calophyllum inophyllum L.). Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta), 8(2), 1-10. https://doi.org/10.20956/ica.v8i2.2466
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References

  1. Permatasari A., Mayangsari, W. and Gunardi, I. (2013). Biodiesel from oil Nyamplung (Calophyllum inophyllum L.) by transesterification reaction catalyst Using K2O/H-Za Based Natural Zeolite. J. Eng. POMITS, 2 (2): 290-295.
  2. Enggawati E. R., and Ediati R. (2013). Utilization Skin Chicken Eggs and Coal Fly Ash as Heterogeneous Catalysts for transesterification reactions Nyamplung Oil (Calophyllum inophyllum L.). J. Sci. Art. POMITS, 2 (1) : 1-6.
  3. Setiawati E., and Edwar F. (2012). Biodiesel Processing Technology of Cooking Oil with Microfiltration Technique and transesterification as Alternative Fuel Diesel Engine. J. Ind. Res., 6 (2) : 117-127.
  4. Christina N., Sungadi E., Hindarso H., and Kurniawan Y. (2013) Biodiesel from oil Nyamplung Using Calcium- Based Catalysts. J. Sci. Wid. Eng., 12 (2) : 26-35.
  5. Santoso H., Kristianto I., and Setyadi A. (2013). Biodiesel Using Heterogeneous Catalysts Bases Made Basic Skin eggs. Leading research universities. Bandung: Institute for Research and Community Service. Universitas Katolik Prahayangan.
  6. Carmo J. A.C., Souza D. L. K. C., Costa D. C. E. F., Longo E., Zamian J. R., and Rocha D. F. G. N. (2009). Production of Biodiesel by Esterification of Palmitic Acido Over Mesoporous Aluminosilicate Al-MCM-41. Fuel, 88 : 461-468.
  7. Mustafa B., and Purwanti E. S. (2011). Biodiesel heat Results catalyst esterification with Al-MCM-41 and Transesterification with Potassium Hydroxide Catalyst Nyamplung Seed Oil (Calophyllum inophyllum L.), Proceedings of the Chemistry-ITS, SK-091304, 1-8.
  8. Lee A. F., Bennett J. A., Manayil J. C., and Wilson K. (2014). Heterogeneous Catalysis for Sustainable Biodiesel Production via Esterification and Transesterification. Chem. Soc. Rev., 43 : 7887-7916.
  9. Singh S., and Patel A. (2014). 12- Tungstophosphoric Acid Supported on Mesoporous Molecular Material : Synthesis, Characterization and Performance in Biodiesel Production. J. Clean. Prod., 72 : 46-56.
  10. Pamata N. (2008). Synthesis of Methyl Ester (Biodiesel) of Hazelnut Seed Oil (Aleurites moluccana) Results Extraction through Ultrasonokimia method. Skripsi. Depok : Department of Chemistry. University of Indonesia.
  11. Rokua H. (2012). Component Analysis of Fatty Acid Undur Undur Sea (Emerita sp.) From the village of Hila Water Central Maluku district. Skripsi. Ambon : Education Program Chemistry. Faculty of Teacher Training and Education. University of Pattimura.
  12. Taba P. (2008). Adsorption of Water and Benzene Vapour in Mesoporous Materials. MAKARA, 12 (2) : 120-125.
  13. Albuquerque M. C. G. (2008). Synthesis, characterization and application of heterogeneous catalysts for the production of biofuels. Dissertation. Fortaleza : Post- Graduation Program in chemistry. Federal University of Ceara.
  14. Pouretedal H. R., and Saedi E. (2014). Dechlorination of 2,4-Dichlorophenol by Zero-Valent Iron Nanoparticles Impregnated MCM-48. Int. J. Ind. Chem., 5 : 77-83.
  15. Pouretedal H. R., and Ahmadi M. (2012). Synthesis, Characterization, and Photocatalytic Activity of MCM-41 and MCM-48 Impregnated with CeO2 Nanoparticles. Nano Lett., 2 (10): 1-8.
  16. Albuquerque M. C. G., Urbistondo I. J., Gonzalez J. S., Robles J. M. M., Tost R. M., Castellon E. R., Lopez A. J., Azevedo D. C. S., Cavalcante C. L. J., and Torres P. M. (2008). CaO Supported on Mesoporous Silicas as Basic Catalysts for Transesterification Reactions. Appl. Catal. A, 334 : 35–43.
  17. Kartika D., and Widyaningsih S. (2012). Optimum catalyst concentration and temperature on the esterification reaction Using Natural Zeolite Catalysts On (ZAH) in Biodiesel from Used Cooking Oil. J. Nat. Idn., 14 (3) :
  18. -226.
  19. Taba P., Natsir H., Fauziah, and Ismail M. (2010). Ion adsorption of Cd (II) by Chitosan-Sillka mesoporous MCM-48. Mar. Chim. Acta., 11 (1) : 13-22.
  20. Sutrisno H., Arianingrum R., and Ariswan. (2005). Titanium mesoporous silicate and silicate-based Mesotruktur hexagonal and cubic structure. J. Math. Sci., 10 (2) : 69-74.
  21. Mansha M., Javed S. H., Kazmi M., and Feroze N. (2011). Study of Rice Husk Ash as Potential Source of Acid Resistance Calcium Silicate. Adv. Chem. Eng. Sci., 1 : 147-153.
  22. Gunawidjaja P. N., Mathew R., Lo A. Y. H., Izquierdo-Barba I., Garcia A., Arcos D., Vallet-Regi M., and Eden M. (2012). Local Structures of Mesoporous Bioactive Glasses and their Surface Alterations in Vitro : Inferences from Solid-State Nuclear Magnetic Resonance. Phil. Trans. R. Soc. A., 370:1376–1399
  23. Federman S. R., Costa V. C., Vasconcelos D. C. L., and Vasconcelos W. L. (2007). Sol-Gel SiO2-CaO-P2O5 Biofilm with Surface Engineered for Medical Application. Mater. Res., 10 (2) : 177-181.
  24. Colovic V. B., Jokanovic, and Jovic N. (2013). Creating of Highly Active
  25. Calcium-Silicate Phases for Application in Endodontics. Sci. Sint., 45 : 341-350.
  26. Yuliana, Veronica J. S., Indraswati N., and Gunantara B. (2005). The use of adsorbent to Reduce Levels of Free Fatty Acid, Peroxide Value and Color Cooking Oil. J. Chem. Eng. Idn., 4 (2):212-218.
  27. Fei Z., Ai S., Zhou Z., Chen X., Tang J., Cui M., and Qiao X. (2014). Enhanced Activity of MCM-48 Based Tin Catalyst for Synthesis of 3- Methylbut-3-en-1-ol by Adjusting the Mesochannel Environment. J. Ind. Eng. Chem., 20 : 4146–4151.
  28. Putri G. E. (2012). Synthesis and Characterization of Cobalt and Copper Catalysts immobilized on mesoporous silica and Catalytic Activity Test in the transesterification reaction of palm oil. Thesis. Padang : Chemistry magister Program. Universitas of Andalas.